Picosecond measurements of geminate charge pair recombination in photoionized liquids
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چکیده
منابع مشابه
Direct femtosecond measurements of single collision dominated geminate recombination times of small molecules in liquids
We report the femtosecond transient absorption spectra of the CHJ photoproduct of the methylene iodide (CH&) photodissociation. The results indicate a disappearance of this photofragment on a z 350 fs time scale in several different solvents. The implication is that in these simple liquids, methylene iodide is undergoing geminate recombination. Recombination yields, but not rates are shown to b...
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The (history independent) autocorrelation function for a hydrogen-bonded water molecule pair, calculated from classical molecular dynamics trajectories of liquid water, exhibits a t(-3/2) asymptotic tail. Its whole time dependence agrees quantitatively with the solution for reversible diffusion-influenced geminate recombination derived by Agmon and Weiss [J. Chem. Phys. 91, 6937 (1989)]. Agreem...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1985
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v85-037